Oil Refining - Passivators
Key to Efficiency and Quality Improvement
What Are Oil Refining Passivators?
In the petroleum refining process, catalytic cracking is a key technology for converting heavy oil into light products such as gasoline and diesel. However, trace metal impurities (such as nickel, vanadium, and copper) contained in crude oil will deposit on the surface of the catalyst during the reaction process, leading to two major problems: catalyst poisoning, where metals reduce the activity and selectivity of the catalyst, thereby lowering refining efficiency; and equipment damage, as vanadium compounds can corrode the reactor lining at high temperatures. Refining passivators are chemical additives specifically designed to alleviate these issues. They form stable complexes with harmful metals, “passivating” their destructive effects, while protecting the performance of the catalyst and extending the service life of the equipment.
Application of Antimony-based Passivators
Antimony-based passivators are applied through a simple, continuous injection system: dosage is calculated based on the metal content in crude oil and the catalyst circulation rate; they are injected into the feedstock before it enters the riser reactor; and their reaction mechanism involves antimony ions bonding with nickel and vanadium to form inert compounds that no longer affect catalyst performance.
Application of Antimony-based Passivators
Antimony-based passivators are applied through a simple, continuous injection system: dosage is calculated based on the metal content in crude oil and the catalyst circulation rate; they are injected into the feedstock before it enters the riser reactor; and their reaction mechanism involves antimony ions bonding with nickel and vanadium to form inert compounds that no longer affect catalyst performance.
Why Antimony-based Passivators Are Industry Preferred
Antimony-based compounds have become the gold standard for oil refining passivators due to their unique chemical properties:
Dual metal control
Antimony effectively passivates both nickel (by reducing its dehydrogenation activity) and vanadium (by forming high-melting-point complexes that prevent corrosion).
Thermal stability
Maintains effectiveness at the high temperatures (500-700°C) typical in catalytic cracking units.
Compatibility
Works seamlessly with various catalyst types (zeolite, alumina) without altering their basic structure.
Cost-efficiency
Requires lower dosages compared to alternative passivators, reducing overall operational costs.
Haihui’s Antimony-based Passivator Products
With 23 years of expertise in antimony-based materials, Luoyang Haihui New Materials offers high-performance passivators tailored for oil refining:
Our flagship product, formulated with high-purity antimony compounds. It efficiently neutralizes nickel and vanadium in FCC (Fluid Catalytic Cracking) units, maintaining catalyst activity and reducing dry gas yields.
We provide tailored solutions based on specific crude oil compositions and refinery operating conditions, ensuring optimal performance for unique refining processes.
Quick Questions
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Yes. Our products are designed to minimize environmental impact, with antimony levels well below regulatory limits in waste streams. They comply with EU REACH and US EPA standards.
Typically, refineries notice improved catalyst activity and product yields within 72 hours of continuous injection.
Absolutely. Our products are specially formulated to handle high-metal residual oils, providing effective passivation even in challenging conditions.
Related Applications
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